In-situ synchrotron investigation of the phases- and their morphology-development in Mg–Nd–Zn alloys

Author:

Tolnai D.1,Sosro T.12,Gavras S.1,Buzolin R. H.3,Hort N.1

Affiliation:

1. Magnesium Innovation Centre , Helmholtz Zentrum Geesthacht, Geesthacht , Germany

2. Brunel Centre for Advanced Solidification Technology , Brunel University London , United Kingdom

3. Institute of Materials Science , Joining and Forming, Graz University of Technology, Graz , Austria

Abstract

Abstract The addition of Zn to the Mg–Nd system improves the yield strength and creep resistance, however its influence on the intermetallic phases in the ternary system is not yet fully understood. Understanding the sequence of phase-formation and phase-evolution during solidification and processing is essential to microstructure design. The solidification was investigated with in-situ synchrotron radiation-diffraction and tomography during cooling from the molten state to 200°C to investigate the phase-formation and transformation characteristics. The solidification starts with α-Mg followed by two distinct intermetallic phases T2 and T3. The results suggest that Zn stabilizes the Mg3Nd phase and accelerates precipitate formation. The dendritic morphology changes during solidification towards coarser shapes, thus impedes feeding and promotes hot tearing.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

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