Cooling conditions for the generation of bulk metallic glasses by droplet deposition

Abstract

Abstract The cooling rate during material processing until glass transition rate is the key parameter for the production of bulk metallic glasses. But in the past, little attention has been paid to advanced production techniques such as deposition of molten metal sprays or spray forming, which offer elevated cooling rates. In this work, cooling conditions during spray forming were investigated due to its utmost importance for producing amorphous structures. Spray forming is treated in this work as a three step cooling process consisting of droplet flight phase, splat phase and deposit phase. All cooling steps were simulated for different droplet sizes. The surface temperature of the deposit was found to play an important role in the production of metallic glasses via spray forming. The simulation model can be used to find suitable spray conditions for the generation of bulk metallic glasses.