Surface tension of a liquid metal–oxygen system using a multilayer free energy model

Author:

Pajarre Risto1,Koukkari Pertti1,Tanaka Toshihiro2

Affiliation:

1. VTT Technical Research Centre of Finland, Espoo, Finland

2. Osaka University, Department of Materials and Manufacturing Science, Graduate School of Engineering, Japan

Abstract

A constrained free energy model for an interfacial system of interacting layers is derived in the regular solution and Redlich–Kister formalisms. Composition and interfacial energies are solved using a model based on the minimisation of the total free energy of the system with a fixed interfacial area. As example cases iron–oxygen and copper–oxygen surfaces and liquid–liquid metal alloy interfaces are studied.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

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