The Effect of Electrolytes on the Interaction of C. I. Reactive Orange 16-Tetradecyltrimethylammonium Bromide

Abstract

Abstract The aim of this study is to investigate the interaction of a cationic surfactant tetradecyltrimethyl ammonium bromide (TTAB) on the electronic absorption spectra of azo dye Reactive Orange 16 (RO16) and to observe the effects of the kind and concentration of electrolytes on these interactions by means of UV-Vis spectroscopy in submicellar and micellar concentration range at a certain temperature (303 K). TTAB affects the electronic absorption spectra of dye solution that is dye-surfactant interaction results into formation of complex and therefore, a decrease in maximum absorption spectra (1.577 at 494 nm). The electrolyte anions cause an increase on the absorbance of TTAB–RO16 ion-pair complex in the following order: Br– > Cl– > SO42– > NO3– > CN– and also for cations; Na+ > K+ > NH4+ > Mg2+. The increase or decrease on absorption spectra of RO16-TTAB solution depends on concentration range of the electrolyte added.