Efficient Synthesis of Nanostructured Poly(aniline-co-m-aminobenzoic acid) Copolymer in Presence of DBSA Surfactant

Abstract

Abstract A new series of novel nanostructured poly (aniline-co-m-aminobenzoic acid) copolymer has been synthesized by chemical oxidative in-situ polymerization method using dodecylbenzene sulphonic acid (DBSA) as a soft template. The synthesized copolymers were characterized by Fourier Transform Infrared spectroscopy, Ultraviolet visible spectroscopy, X-ray diffraction and scanning electron microscopy. The infrared spectrum shows the characteristic peaks confirming the formation of the copolymer. The ultraviolet visible spectrum shows the π to π∗ transition and n to π∗ transition. X-ray diffraction pattern confirms the amorphous nature of the polymer. Scanning electron microscopic images show the new morphology of spherical granular sponge like structures in the range of 100 to 200 nm. Conducting properties of the copolymers were studied using four probe method. Copolymers doped with DBSA showed an increased conductivity in the order of 10–4 S/cm. These copolymers are found to be more soluble in polar solvents comparing to polyaniline homopolymer.