Determination of Liquidus Temperature in Sn–Ti–Zr Alloys by Viscosity, Electrical Conductivity and XRD Measurements

Author:

Plevachuk Yuriy1,Mudry Stepan1,Sklyarchuk Vasyl1,Yakymovych Andriy1,Korolyshyn Andriy1,Shtablavyy Ihor1,Kulyk Yuriy1,Klotz Ulrich E.2,Liu Chunlei34,Leinenbach Christian3

Affiliation:

1. Ivan Franko National University, Department of Metal Physics, Lviv, Ukraine

2. FEM, Research Institute Precious Metals & Metals Chemistry, Schwäbisch Gmünd, Germany

3. Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory of Joining & Interface Technology, Dübendorf, Switzerland

4. Now at: ABB Research Center, Baden-Dättwil, Switzerland

Abstract

Abstract The Sn – Ti – Zr system is an important subsystem for Cu based active brazing filler metals. Experimental results on this system, however, are rather scarce. The diagram is rather uncertain regarding most of the liquidus, especially on the Sn rich side. In this work, the atomic structure and temperature dependence of structure-sensitive physical properties (dynamic viscosity and electrical conductivity) of liquid Sn – Ti – Zr alloys in the Sn-rich corner were investigated in a wide temperature range with special attention to the melting – solidification region. The results allowed the liquidus line position to be specified.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

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