Carboxylate-Terminated Double-Hydrophilic Block Copolymer as an Effective Inhibitor for Carbonate and Sulphate Scales

Abstract

Abstract For the control of carbonate and sulphate scales, a new type of green scale inhibitors AQn was synthesized. The thermal stability and the molecular weight of the copolymers were investigated by thermal gravimetric analysis and gel permeation chromatography, respectively. The anti-scale property of the AQn copolymers towards CaCO3 and CaSO4 in the artificial cooling water was studied through static scale inhibition tests. The results show that both CaCO3 and CaSO4 inhibition increase with increasing the degree of polymerization of AQn from 5 to 15. The dosage of AQn plays also an important role on CaCO3 and CaSO4 inhibition. Surface morphology characterization of CaCO3 and CaSO4 was investigated with combination of scanning electronic microscopy (SEM), transmission electron microscopy (TEM) and X-ray powder diffraction (XRD) analysis. An inhibition mechanism is proposed that the interactions between calcium and polyethylene glycol (PEG) are the fundamental impetus to restrain the formation of the scale in cooling water systems.