Author:
Malik Suzanna,Saha Bidyut
Abstract
AbstractThe present paper describes the kinetics and mechanism for oxidation of D-arabinose by Cr(VI) in the presence of a micellar media. The anionic surfactant sodium dodecyl sulphate (SDS) and nonionic surfactant Triton-X-100 (TX-100) accelerate the process while the cationic surfactant N-cetylpyridinium chloride (CPC) retards the reaction. A suitable mechanism has been proposed. The reaction constants involved in different steps of the mechanism have been calculated. Formic acid and erythronic acid were reported as the products of oxidation of the sugar.
Subject
Condensed Matter Physics,General Chemical Engineering,General Chemistry
Cited by
6 articles.
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