Bowing Phenomenon in Double Bubble Tubular Film Processing for PA 6

Author:

Takashige M.1,Kanai T.2,Yamada T.3

Affiliation:

1. Idemitsu Unitech Co., Ltd., Hyogo, Japan

2. Idemitsu Petrochemical Co., Ltd., Chiba, Japan

3. Kanazawa University, Ishikawa, Japan

Abstract

Abstract This report is to discuss the bowing phenomenon and the sag elimination tension for biaxial oriented PA 6 film process, which consists of double bubble tubular film process and the thermosetting tentering. The bowing phenomenon does not occur in the heat set of the triple bubble tubular process. However, there is a serious problem of the bubble stability when the sufficient thermosetting by the tubular process is carried out, so the heat set by the tenter process is required. The bowing phenomenon arises when the annealing is carried out by the tenter method. The bowing distortion becomes large when the annealing temperature is high and film relaxation ratio is large. It is possible to reduce the bowing distortion when thermosetting is carried out in a two-step tenter process. The shrinkage stress of the stretched film was relaxed in the heat treatment during the second step whose temperature is higher than the first one. A two-step heat treatment was able to decrease the bowing distortion compared with the one-step heat treatment. When the bowing phenomenon occurred, shrinkage percentage in hot water changes along the cross-direction of a film. The humidity expansion coefficient in the film which increases as the increasing shrinkage percentage in hot water is related to the molecular orientation. The sag also increased with increasing the bowing distortion. The bowing distortion and the sag elimination of tension have proportional connection.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Polymers and Plastics,General Chemical Engineering

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