High-activity of Pd catalyst supported on antimony tin oxide for hydrogen peroxide electroreduction

Author:

Sun Limei1,Liu Zongrui1,Bao Yingrong1,Li Hongxia1,Bao Wuyunga1

Affiliation:

1. College of Chemistry and Chemical Engineering , Inner Mongolia University for the Nationalities, Tongliao , China

Abstract

Abstract Pd electrocatalysts supported on antimony tin oxide and Vulcan XC-72 were both synthesized via a modified sodium borohydride reduction method. The catalysts were characterized by means of powder X-ray diffraction and cyclic voltammetry. Linear sweep voltammetry, open circuit potential curves and chronoamperometry were employed to evaluate the activities of the catalysts. The results show the particle size of Pd in the Pd electrocatalysts supported on antimony tin oxide catalyst is about 2.5 nm, which is smaller than that of the Pd electrocatalysts supported on Vulcan XC-72 (about 6.3 nm), and the surface area of the Pd electrocatalysts supported on antimony tin oxide electrode is larger than that of the Pd electrocatalysts supported on Vulcan XC-72 electrode. The Pd catalyst supported on antimony tin oxide shows superior performance to the catalyst supported on Vulcan XC-72.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

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