Formation of Mixed Micelles of the Environmentally Acceptable Oxy-Diester-Linked Gemini Surfactants with Brij 58

Abstract

Abstract Three oxy-diester-linked cationic gemini surfactants (2,2′-[(oxybis(ethane-1,2-diyl))bis(oxy)]bis(N-alkyl-N,N-dimethyl-2-oxoethanaminium) dichloride, Cm-DEG-Cm (m = 12, 14, 16), were synthesized. The physicochemical properties of the gemini surfactants and their mixtures with Brij 58 were studied by surface tension measurements at various mole fractions and 30°C. The critical micelle concentration (CMC) of the gemini surfactants are smaller than that of their corresponding single-chain counterparts having the same number of carbon atoms in the hydrophobic tail versus polar head. At all investigated compositions, the experimentally obtained CMC values of the surfactant mixtures are smaller than the CMCideal (ideal CMC – CMC of the solution at ideal state); the lower CMC of the mixed systems compared to those the individual surfactants and the negative β values (for both the mixed micelles and monolayers) indicate a synergistic interaction among both the surfactant components. The interaction parameters (βm and βσ) of the mixed surfactant systems were evaluated by using theoretical models. Negative values of β imply an overall attractive force in the mixed state. Also, the free excess energy of mixing was found to be negative for all the systems.