Abstract
Abstract
Silica gel 60 F254 plates were used with mixed aqueous-organic solvent systems consisting of dioxan and lithium chloride for the chromatography of three nonionic surfactants. The resolution of coexisting Triton X-100, Brij-57 and Brij-78 was achieved with the solvent system 1,4-dioxan:1% aqueous LiCl (40:60, v/v). The effect of concentration of Li+ ions in the solvent system on the mobility of the three surfactants was studied. The interference on the resolution of the mixture of Triton X-100, Brij-57 and Brij-78, due to the presence of metal cations as impurities, is also examined. The limits of detection of Triton X-100, Brij-57 and Brij-78 estimated were 0.075, 0.150 and 0.20 μg/zone respectively. The practical applicability of proposed method was tested for the identification of three coexisting nonionic surfactants after their separation from the spiked aqueous systems.
Subject
Condensed Matter Physics,General Chemical Engineering,General Chemistry
Cited by
3 articles.
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