Experimental investigation of phase equilibria in the Nb–Si–Ta ternary system

Author:

Li Jian12,Wang Cuiping12,Yao Jun12,Yang Shuiyuan12,Kang Yongwang3,Shi Zhan12,Liu Xingjun12

Affiliation:

1. Department of Materials Science and Engineering , College of Materials, Xiamen University, Xiamen , P. R. China

2. Fujian Provincial Key Laboratory of Materials Genome , Xiamen University, Xiamen , P. R. China

3. Science and Technology on Advanced High Temperature Structural Materials Laboratory , Beijing Institute of Aeronautical Materials, Beijing , P. R. China

Abstract

Abstract The phase equilibria in the Nb–Si–Ta ternary system at 1 373 K, 1 473 K and 1 573 K were investigated by means of back-scattered electron imaging, electron probe microanalysis and X-ray diffraction. The isothermal sections at 1 373 K, 1 473 K and 1 573 K consist of two three-phase regions and seven two-phase regions, without any ternary compounds. The compounds of NbSi2 and TaSi2, αNb5Si3 and αTa5Si3 form continuous solid solutions, respectively. The solubilities of Nb in Ta3Si and Ta2Si phases are extremely large, whereas the solubility of Si in the β(Nb, Ta) phase is relatively small.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Physical and Theoretical Chemistry,Condensed Matter Physics

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