Abstract
Polyaniline (PANI) has an exclusive representation probably owing to the fact that it has new applications in several fields of nano-technology. It is known for its straightforward synthesis process, high environmental stability and it can be easily doped by different acids. This chapter deals with the synthesis of PANI by several methods in which oxidative polymerization is the simplest and the most highly studied process. The synthesized PANI thin films can be deposited on different substances by a number of chemical and physical-based methods. These PANI thin films have been characterized by different techniques. FTIR and Raman spectroscopy used for structural analysis of synthesized PANI thin films while the crystalline nature determined by X-ray diffraction (XRD). Similarly, SEM, TEM, and AFM have been used for surface analysis of PANI thin films. The thermal and optical characteristics of PANI thin films studied by TGA and optical absorbance spectroscopy, respectively. The cyclic voltammetry (CV) curve gives information about the electrochemical reaction rate and the redox potential of PANI thin films.