Amorphous Silica Production from Serpentine and its Techno-Economic Analysis

Author:

Çakan Yalçın1ORCID,Gönen Mehmet2ORCID

Affiliation:

1. Betek Boya ve Kimya San. AŞ.

2. SÜLEYMAN DEMİREL ÜNİVERSİTESİ

Abstract

The production of silica from the reaction of serpentine mineral with sulfuric acid has been investigated. Silica production process was developed by using optimum parameters of 67.3 °C temperature, 4.8 M acid concentration and 57.1 min. reaction time. Techno-economic analysis of the silica production process was made using a SuperPro Designer software (Version 9.0). Simulation has been performed for different annual plant capacities between 4,000 t and 16,000 t. The optimum production cost of silica was obtained for an annual plant capacity of 12,000 t. The total capital investment and operating costs for silica production facility designed was calculated as US$40,247.000 and US$4.24/kg, respectively. The payback period of the facility investment was determined as 4.8 years. The tailing waste of chrome ore could be used as raw material to produce silica and magnesium sulfate in an economic way.

Publisher

The Turkish Chemical Society

Reference21 articles.

1. Ballhorn, R. and Franke, W., (1996), EP0791559A1. European Patent Office, Frankfurt, DE.

2. Carmignano, O. R. D., Vieira, S. S., Brandão, P. R. G., Bertoli, A. C., & Lago, R. M. (2020), Serpentinites: Mineral structure, properties and technological applications. Journal of the Brazilian Chemical Society, 31, 2-14.

3. Chen, Y., Yang, X., Wu, L., Tong, L., & Zhu, J. (2023). Recovery of Mg from H2SO4 Leaching Solution of Serpentine to Precipitation of High-Purity Mg(OH)2 and 4MgCO3·Mg(OH)2·4H2O. Minerals, 13(3), 318

4. Çakan, Y. (2022), Serpantin mineralinden amorf silica üretimi ve proses şartlarının optimizasyonu. (Publication No: 765850) (Master’s dissertation, Süleyman Demirel University)

5. Çakan, Y., & Gönen, M. (2022), Serpantin Mineralinden Amorf Silika Üretimi ve Proses Şartlarının Optimizasyonu. Yekarum, 7(2), 33-47.

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