Author:
Baran Enrique J.,Parajón-Costa Beatriz S.,Echeverría Gustavo A.,Piro Oscar E.
Abstract
<p><strong>SYNTHESIS, STRUCTURAL AND SPECTROSCOPIC CHARACTERIZATION OF THALLIUM(I) ACESULFAMATE</strong></p><p><strong> </strong></p><p> The new acesulfamate salt, TlC<sub>4</sub>H<sub>4</sub>NO<sub>4</sub>S, was prepared by reaction of acesulfamic acid and thallium(I) carbonate in aqueous solution. Its crystal and molecular structure was determined by single crystal X-ray diffraction methods. The substance crystallizes in the monoclinic space group <em>P2<sub>1</sub>/a</em>, with unit cell parameters <em>a </em>= 7.5844(4) Å, <em>b</em> = 9.7268(5) Å, <em>c</em> = 10.8105(5) Å, <em>β</em> = 105.174(6)°, and <em>Z</em>=4 molecules per unit cell, and is isostructural with the corresponding sodium, potassium, rubidium and cesium salts. The FTIR and Raman spectra of the compound are also recorded and briefly discussed.</p>
Publisher
Society of Chemists and Technologists of Macedonia
Subject
General Chemical Engineering,General Chemistry
Cited by
13 articles.
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