Uncompleted Fullerenelike Structures: Synthesis and Chracteristics

Abstract

The literature is considering completely formed fullerenes as usually. Without attentions have been left uncompleted ones, and their properties are practically unknown. Such structures may be received at arc discharge synthesis in the limited space with short time of synthesis. Here synthesis was made at arc discharge chamber with little radius and less gas flow. The time-of-flight mass spectrum synthesized product on m/z size showed containing of hydrated uncompleted-composite fullerene. They were like with structures: C54H4, C56H4, C56H8, C68H4 and other. A presence at mass spectrum of abnormal structures was manifested in form of doublet many-peaks lines. They also confirmed termperature-formating of new bonds with successive griping valence bonds with poliin structures at arc discharge. From mass spectrum, on base of Mendileive’s chemical plate was supposed the way forming conjectural structure. The MS-picture was confirmed with estimation for forming many-peaks abnormal poliin like structures.