Chemical and mineral composition of sulfide nodules from the Mikhaylovsky and Belousovsky ancient mines, Orenburg Gis-Urals

Author:

Blinov I.A.1

Affiliation:

1. South Urals Federal Research Center of Mineralogy and Geoecology UB RAS, Institute of Mineralogy, Miass, Chelyabinsk oblast, 456317 Russia; blinov@mineralogy.ru

Abstract

Cu-sulfde and rare Fe-sulfde nodules up to 2–5 cm in size are found in gray marl siltstones, which occur in a sequence of Permian sandstones of Orenburg Cis-Urals. The Cu-sulfde nodules are characterized by high Cu content (>20 %) and low contents of trace elements (Fe <1.2 %, As, Ag, V, and Pb <130 ppm). They are composed of Cu sulfdes (minerals of the chalcocite group and covellite) with minor barite and mottramite. The Cu sulfdes are transformed to malachite and, to a lesser degree, to chrysocolla and brochantite. The decomposition of Ag-bearing Cu sulfdes leads to the formation of a Ag sulfde. The Fe-sulfde nodules of the Belousovsky mine are composed of pyrite. In the oxidation zone, pyrite is replaced by ferrous opal; single grains of plumbogummite are associated with Fe hydroxides.

Publisher

South Urals Federal Research Center for Mineralogy and Geoecology of the Urals Branch of the RAS

Reference18 articles.

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2. Bogdanov S.V., Tkachev V.V., Yuminov A.M., Avramenko S.V. (2018) [Geoarchaeological system of historical copper mines of the Cis-Ural (Kargaly) steppe mining and metallurgical center]. Geoarkheologiya i arkheologicheskaya mineralogiya [Geoarcheology and archaeological mineralogy]. Miass, IMin UB RAS, 121– 133. (in Russian).

3. Emmons W. (1935) [Secondary enrichment of ore deposits]. M., L .: Joint scientifc and technical publishing house NKTP USSR. 479p. (in Russian)

4. Gablina I.F. (1994) Metamorphism and supergenesis of Cu sandstones and shales. Abstract of Dissertation of Doctor of Geological-Mineralogical Sciences. Moscow, 45 p. (in Russian).

5. Gablina I.F. (2006) [Sulfdes of copper and iron at diferent stages of lithogenesis]. Materialy 4-go Vserossiyskogo litologicheskogo soveshchaniya [Materials of the 4th All-Russian lithological meeting]. Moscow, GEOS, 2, 136–139. (in Russian).

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