Pd/Cu-Catalyzed Coupling of Cyclopentadienyliron Dicarbonyl Iodide and Methyl Propiolate in Synthesis of Cp(CO)₂Fe-C≡C-COOMe
Author:
Verpekin Victor V.1,
Kondrasenko Alexander A.1
Affiliation:
1. Institute of Chemistry and Chemical Technology SB RAS FRC ‘‘Krasnoyarsk Science Center SB RAS”
Abstract
The conditions of successful iron-carbon coupling in the reaction between cyclopentadienyliron dicarbonyl iodide and methyl propiolate upon the Pd/Cu catalysis were determined. A new high-yield synthetic approach to the methoxycarbonylethynyl iron complex Cp(CO)₂Fe-C≡C-COOMe were developed
Publisher
Siberian Federal University
Subject
General Chemical Engineering,General Chemistry