Crystallization and magnetic properties of amorphous iron–chromium oxide nanoparticles synthesized by sonochemistry

Author:

Nguyen Dang Phu,Tran Quoc Tuan,Trinh Xuan Sy,Hoang Thanh Cao,Nguyen Hoang Nam,Nguyen Hoang Hai

Abstract

Abstract Amorphous iron–chromium oxide Fe 2−x Cr x O 3 (x=0, 0.05, 0.10, 0.15, 0.20) nanoparticles were synthesized by sonochemical method at 80 °C. Crystallization process of the annealed samples showed a strong ferromagnetic behavior due to the existence of the maghemite phase. The effect of chromium replacing iron in the crystallization process of Fe 2−x Cr x O 3 nanoparticles was systematically studied by adjusting initial concentration of Cr 3+. The activation energy of the samples deduced from thermal analysis and increased with doping chromium showed that the existence of chromium can significantly slow down the ageing effect of the amorphous iron oxide.

Publisher

IOP Publishing

Subject

Electrical and Electronic Engineering,Industrial and Manufacturing Engineering,General Materials Science

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