Topical review: characterization of chalcopyrite CuGa(In)Te2 compounds for high thermoelectric performance

Abstract

Abstract The chalcopyrite compound CuGa(In)Te2 has garnered significant attention due to its safe elemental composition and high thermoelectric potential. Optimizing the carrier concentration and reducing the lattice thermal conductivity of CuGa(In)Te2 can significantly enhance its thermoelectric performance. In this mini-review, we analyze the electronic and phonon structures of CuGa(In)Te2, summarize and categorize the representative methods employed in recent years to improve its thermoelectric performance. Our analysis reveals that reducing thermal conductivity has a more significant impact on enhancing the ZT value of CuGa(In)Te2 compared to increasing the power factor. In conclusion, we outline potential challenges and provide a brief outlook, offering valuable insights into the design of CuGa(In)Te2 chalcopyrite compounds as high-performance thermoelectric materials.