Generation and optimization of cross-sections for electron-C4F7N collisions

Abstract

Abstract A complete and consistent set of electron-neutral collision cross-sections for the novel insulating gas C4F7N is reported. The set is composed of a combination of cross-sections previously reported in literature, optimized via a genetic algorithm in conjunction with a multi-term Boltzmann equation solver, and calculated ab initio using the R-matrix code Quantemol-EC. The finalized set accurately reproduces reported macroscopic rate and transport coefficients as well as Townsend coefficients and critical electric field strengths in C4F7N and its mixtures with nitrogen, carbon dioxide, and argon.