Abstract
Abstract
Solution-processed organic photovoltaic (OPV) as a new energy device has attracted much attention due to its huge potential in future commercial manufacturing. However, so far, most of the studies on high-performance OPV have been treated with halogenated solvents. Halogenated solvents not only pollute the environment, but are also harmful to human health, which will negatively affect the large-scale production of OPV in the future. Therefore, it is urgent to develop low-toxic or non-toxic non-halogen solvent-processable OPV. Compared with conventional fullerene OPVs, non-fullerene OPVs exist with stronger absorption, better-matched energy levels and lower energy loss. Processing photoactive layers with non-fullerenes as the acceptor material has broad potential advantages in non-halogenated solvents. This review introduces the research progress of non-fullerene OPV treated by three different kinds of green solvents as the non-halogenated and aromatic solvent, the non-halogenated and non-aromatic solvent, alcohol and water. Furthermore, the effects of different optimization strategies on the photoelectric performance and stability of non-fullerene OPV are analyzed in detail. The current optimization strategy can increase the power conversion efficiency of non-fullerene OPV processed with non-halogen solvents up to 17.33%, which is close to the performance of processing with halogen-containing solvents. Finally, the commercial potential of non-halogen solvent processing OPVs is discussed. The green solvent processing of non-fullerene-based OPVs will become a key development direction for the future of the OPV industry.
Funder
the National Natural Science Foundation of China
the Strategic Priority Research Program of Chinese Academy of Sciences
the National Key Research and Development Program of China
the PEIYANG Young Scholars Program of Tianjin University
National Natural Science Foundation of China
Subject
Electrical and Electronic Engineering,Mechanical Engineering,Mechanics of Materials,General Materials Science,General Chemistry,Bioengineering
Cited by
20 articles.
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