Effect of praseodymium in cation distribution, and temperature-dependent magnetic response of cobalt spinel ferrite nanoparticles

Abstract

Abstract This work reports cation distribution, magnetic, structural, and morphological studies of rare-earth Pr doped cobalt ferrite nanoparticles CoFe2−x Pr x O4 (x = 0, 0.02, 0.04, 0.06 at%) fabricated by sol-gel auto-combustion method. X-ray diffraction analysis, field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), and Fourier-transform infrared (FTIR) microscopy were utilized to study the structural and morphological characteristics of the prepared samples. Rietveld refinement by the Material Analyses Using Diffraction (MAUD) software showed the formation of mono-phase cubic spinel structure with Fd-3m space group; however, there was a trace of impure PrFeO3 phase for the sample CoFe1.96Pr0.04O4 (x = 0.06). Cation distribution was inferred from the XRD patterns using MAUD program. FESEM analysis revealed the spherical-shaped particles with dimensions close to the data extracted from XRD analysis and HRTEM images confirmed it. FTIR measurements revealed the presence of two prominent stretching vibrational modes confirming the successful formation of ferrite spinel structure. Magnetic properties of the nanoparticles were measured at two different temperatures 300 K and 10 K. For the low temperature of 10 K a high sensitive measurement method as Superconducting Quantum Interference Device (SQUID) magnetometry was used and Vibrating Sample Magnetometer (VSM) recorded the magnetic data at 300 K. Comparison of the magnetic results exhibited a significant enhancement with temperature drop due to the reduction in thermal fluctuations. Paramagnetic nature of rare-earth ions may be the main reason for M S decrement from 76 emu g−1 (x = 0.0) to 60 emu g−1 (x = 0.02) at 300 K. At 10 K, the estimated cation distribution played a vital role in justification of obtained magnetic results. All the obtained data showed that the synthesized magnetic nanoparticles can be implemented in permanent magnet industry and information storage fields, especially when it comes to lower temperatures.