Abstract
Abstract
A thermodynamic models of binary system carbon dioxide (1) - mixture (monoethylene glycol (MEG)/water) (2) at pressure up to 5 bar and temperatures (288-348 K) are established using SRK and PR equation of state (EOS). Modified van der Waal’s and quadratic mixing rules are coupled with the two Equation of state. Prediction of carbon dioxide in pure water and MEG were studied as well using same equations. Average absolute deviation in liquid-phase compositions percentage AADx % used for adjustable parameter optimization. The predicted results are showed very good agreement with the experimental data in all the systems examined. Quadratic mixing rule in all systems gives AADx % lower than Modified van der Waal’s and the values differences can be ignored.