A Comparative Study of Chemical Material Additives On Polyacrylamide to Treatment of Waste Water in Refineries

Abstract

Abstract During extractions industries, particularly oil companies in Iraq such Ahdab oil field that consuming a huge amount of water which led to producing oil-contaminated water thus it made dangerous on natural life (agricultural lands and rivers) and infrastructural through cause complex corrosion for pipelines and equipment’s. Coagulation and flocculation processes are efficient to separate oil content and the suspended solids portion from the waste water. During the study have been used additives of the ferrous sulphate, aluminum sulphate and calcium sulphate in the range (10-40) ppm, for the processes of coagulant, and polyelectrolyte-(polyacrylamide) additional to the flocculent has used. Additives materials within the coagulant and flocculant treatments have been led to obtaining of the optimal eliminations amount total suspended solids, oil contents and others. It has been noted that the percentage of oil removing about 86.67%, 85.5% and 79.6 via using 30 ppm coagulant dose of ferric sulphate, aluminum sulphate and calcium sulphate with 2.5 mg/L of polyacrylamide at pH = 6.86 and room temperature (25 °C). Generally, ferrous sulphate has highly ability to adsorbing the oil particulates and suspended solids of the refinery wastewater, as well the reducing economic cost of water treatments.