Ultrashort Ne+ ion pulses for use in pump–probe experiments: numerical simulations

Abstract

Abstract A time resolved experiment to investigate the ultrafast dynamics following an ion impact onto a solid surface requires an ultrashort ion pump pulse in combination with a properly synchronized and time resolved probe. In order to realize such an experiment, we have investigated a strategy to use femtosecond laser photoionization of atoms entrained in a pulsed supersonic jet for the production of sufficiently short ion pulses. While the generation of Arq+ ions was targeted in previous work, it has in the meantime been demonstrated that argon is not suitable due to extensive cluster formation in the supersonic expansion. Here, we therefore present numerical simulations investigating the use of neon as a precursor gas and show the feasibility of pulses containing up to ∼1000 Ne+ ions at keV energies and picosecond duration. In the process, we demonstrate that space charge broadening can be significantly reduced by detuning the flight time focusing conditions of an ion bunching system. Moreover, the results show that a controlled variation of the buncher geometry and potentials permits the generation of picosecond pulses at variable ion energy between 1 and 5 keV.