Diatomic molecule in a strong infrared laser field: level-shifts and bond-length change due to laser-dressed Morse potential

Abstract

Abstract We present a general mathematical procedure to handle interactions described by a Morse potential in the presence of a strong harmonic excitation. We account for permanent and field-induced terms and their gradients in the dipole moment function, and we derive analytic formulae for the bond-length change and for the shifted energy eigenvalues of the vibrations, by using the Kramers–Henneberger frame. We apply these results to the important cases of H2 and LiH, driven by a near- or mid-infrared laser in the 1013 W cm−2 intensity range.