Hexagonal sheet Ag and Ag nanoparticle inside 3D-TiO2 NTAs decorated Ti gauze by electrodeposition

Abstract

Abstract Noble metal nanoparticles have attracted extensive attention by many researchers because of their optical, electrical and magnetic advantages. Half hexagon sheet Ag and Ag nanoparticles inside 3D-TiO2 nanotube arrays (NTAs) on Ti gauze was firstly synthesized by electrodeposition. The addition has a great influence on the morphology of Ag. When Ag hexagonal side length reached a maximum of 2 μm for 20 pluses, hexagonal Ag would transform oval Sphere with depositional pulses continuing increases, Ag nanoparticle inside 3D-TiO2 NTAs also were found, and the Ag modified NTAs for 20 pulses with the best photo-catalytic activity degraded methyl orange (MO) under solar light irradiation. Due to 3D-TiO2 NTAs supporting Ag catalyst, which is a benefit for recycling after the catalyst. This work is expected to provide a fundamental guide for the design of novel morphology catalysts on Ti gauze, which is conducive to recycling.