The comparative analysis of the solid-state 31P NMR spectra of Re-Pt vinylidene complexes-Reference-Cited by-同舟云学术

The comparative analysis of the solid-state 31P NMR spectra of Re-Pt vinylidene complexes

Published:2019-12-01 Issue:2 Volume:1399 Page:022028
ISSN:1742-6588
Container-title:Journal of Physics: Conference Series
language:
Short-container-title:J. Phys.: Conf. Ser.

Author:

Smolyarov K T,Volkov N V,Matsulev A N,Kondrasenko A A

Abstract

Abstract The two vinylidene complexes Cp(CO)2 RePt(μ-C=CHPh)(PPh3 )(CO) and Cp(CO)2 RePt(μ-C=CHPh)(PPh3 )2 and their precursors PPh3 and P(PPh3 )4 were studied by solid-state nuclear magnetic resonance. We analysed 31P cross-polarization spectra acquired in static conditions and with magic angle spinning. The chemical shift tensors of each sample were determined by fitting their spectra using SIMPSON simulations.

Publisher

IOP Publishing

Subject

General Physics and Astronomy

Link

https://iopscience.iop.org/article/10.1088/1742-6596/1399/2/022028/pdf

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