Investigation The Quantum Chemical Parameters and Electronic Transition States for Suggested Platinum Metal Complex

Abstract

Abstract SDD basis sets were used in current work together with the hybrid B3LYP functional to investigate of suggested platinum metal complex. The results showed the complex under study likes the cisplatin complex in many of it is properties, they have large band gap with low electrochemical hardness and electronic softness. Based of cis-platin, the substitute of iso-indene rings in place of amine groups in cis-platin unaffected on the geometrical parameters of bonding the central platinum metal with chlorine atoms and the ligands, the suggested platinum complex keeps the coordination of metal complex with values of frontier molecular orbitals close to those for cisplatin. π →π* transition of states were appeared in the behavior of absorption spectrum for the complex under study.