Sensor Fabrication for Determination of Cadmium Using Nafion/Ionic Liquid/Graphene Composite with Thick Film Technology

Abstract

Abstract The cadmium (Cd (II)) detection sensor consists of working electrode, counter electrode and reference electrode made with thick film technology on sensitive material-based carbon electrodes (G/N/IL/SPCE) and coated with Bismuth film. Carbon (C) paste, Ag | AgCl is used as working electrode, counter electrode and reference electrode material on alumina substrate by screen printing. The working electrode was doped with Graphene (G), Nafion (N) and Ionic liquid (IL). Furthermore, Bismuth-Film (BiF) is coated with electrodeposition on the surface of the working electrode. Electrode characterization with SEM is conducted to see the morphology of sensitive materials. It showed that the particles were distributed evenly on the surface of the electrode with spherical particles. Analysis using EDS shows the element’s atomic composition is C 91.57%, N 3.48%, O 3.23%, Bi 0.01%. The performance of the cadmium sensor was tested with a potentiostat in a standard Cd solution with a concentration of 0.005 mgL-1 – 1 mgL-1 indicating an average output voltage range of 10.36 volts - 10.37 volts. This can be explained that the sensor can detect Cd (II) content properly according to performance.