The influence of Nano-composite metal oxides on the thermal decomposition performance of RDX

Abstract

Abstract In order to investigate the effect of nano-composite metal oxides on the thermal decomposition performance of hexogen (RDX), this study prepared nano nickel-iron (NFO), nickel-cobalt (NCO), and nickel-iron-cobalt (NFCO) composite oxides by liquid-phase co-precipitation method. The precursor of Prussian blue analogs was synthesized and then calcined in air at 600°C. The addition of nano nickel-iron (NFO), nickel-cobalt (NCO), and nickel-iron-cobalt (NFCO) composite oxides to RDX has a significant impact on its thermal decomposition process. The peak exothermic temperatures were delayed by 8.4°C, 8.5°C, and 8.3°C, respectively, after adding the nano-composite metal oxides, and the heat release also increased to a certain extent. Among them, the addition of NCO nano-composite metal oxides had the greatest impact on the exothermic peak temperature of RDX, while the addition of NFCO nano-composite metal oxides resulted in the largest increase in heat release. This indicates that the addition of NFO, NCO, and NFCO to RDX altered the thermal decomposition reaction process to some extent.