Innovative proposal for N2 capturing in Liquid Argon using the Li-FAU molecular Sieve

Author:

Cardoso DilsonORCID,Segreto EttoreORCID,Cruz IvanaORCID,da Silva Edilene DeiseORCID,Zapelini Iago WilliamORCID,Gonçalves Rosembergue G.ORCID,Freitas G.S.ORCID,Caffer Ana Maria,Souza J.C.,Christovam D.S.ORCID,Mazali Italo O.ORCID,Reis CristhianeORCID,Assaf ElisabeteORCID,Assaf José MansurORCID,Soccol Renato,Bianchi PedroORCID,Wiederhecker GustavoORCID,Noriler DirceuORCID,dos Santos Cezar Rodrigo Aguiar,Brant KrystalORCID,Fontes MagdaORCID,Oliveira N.F.,Correia DanielORCID,Frandini Heriques,Demolin Frederico,Augusto André,Doubnik RozaORCID,Adamowski Mark,Montanari DavidORCID,Alegre Thiago P.M.ORCID,Adriano CrisORCID,Machado Ana AméliaORCID,Pagliuso P.G.ORCID

Abstract

Abstract In this work, we unveil the potential of nitrogen (N2) adsorption from Liquid Argon (LAr) through the molecular sieves (zeolites) Li-FAU Adsorbents. We report detailed studies about N2 gas adsorption at T = 89 K using a commercial Micromeritics ASAP-2420 equipment and N2 purification from LAr using the Purification Cryostat (PuLArC) at IFGW/Unicamp. We argue that the N2 adsorption by the Li-FAU is possible thanks to the stronger interaction of N2 with the lithium cations present in zeolite Li-FAU. In fact, the experiments performed in PuLArC have unequivocally shown that the Li-FAU adsorbent was capable of capturing N2, reducing a N2 contamination of 20–50 ppm to 0.1–1.0 ppm in 1–2 hours of circulation time in LAr for several runs. This result demonstrated the great potential of the Li-FAU adsorbent for N2 capturing in LAr and invoke further tests of this material in larger scale LAr cryostats in order to confirm the innovative proposal of using the Li-FAU molecular sieve in replacement of Molecular Sieve 4A, currently used in LAr cryostats for neutrino experiments.

Publisher

IOP Publishing

Reference23 articles.

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