The impact of particulate pollution control on aerosol hygroscopicity and CCN activity in North China

Abstract

Abstract Air quality has greatly improved in China owing to the strict control policy enforced during the last decade. This study investigated the impact of particulate pollution control on aerosol hygroscopicity and cloud condensation nuclei (CCN) activity in North China based on several data sources. The mass concentration of particles with an aerodynamic diameter smaller than 2.5 µm (PM2.5) decreased by one third from the summer of 2014 to the summer of 2020 in Xinzhou (XZ). The mass fractions of aerosol chemical components in PM2.5 also clearly changed, showing an increase in hydrophilic inorganics and a decrease in hydrophobic organics and black carbon from 2014 to 2020. Measurements of the particle number size distribution in XZ indicate that the occurrence frequency of new particle formation (NPF) events decreased significantly from 2014 to 2020, leading to a reduction in the generation of daytime ultrafine particles. The weakened NPF and increasing influence of morning and evening peak emissions modified the diurnal variations of the number concentration of condensation nuclei (N CN) and CCN (N CCN). The aerosol activation ratio was always higher in the summer of 2014 than in the summer of 2020. These results demonstrate that particulate pollution control can decrease N CN and N CCN but enhance aerosol hygroscopicity and activation ability.