Physicochemical Studies of PMR Resins. I: Reaction Mechanism and Kinetics at Room Temperature-Reference-Cited by-同舟云学术

Physicochemical Studies of PMR Resins. I: Reaction Mechanism and Kinetics at Room Temperature

Published:1991-04 Issue:2 Volume:3 Page:113-136
ISSN:0954-0083
Container-title:High Performance Polymers
language:en
Short-container-title:High Performance Polymers

Author:

Grenier-Loustalot Marie-Florence,Grenier Philippe¹

Affiliation:

1. Laboratoire de Chimie Organique Physique, CNRS URA 474, GDR 966, Helioparc Pau-Pyrenees, 2 rue P. Angot, 64000 Pau, France.

Abstract

The reaction mechanism and kinetics of PMR 15 resin (polymerization of monomeric reactants) were studied at low and room temperature using models thoroughly characterized by nuclear magnetic resonance (1H, 13C liquid and solid state) and liquid chromatography. The results indicate a difference in reactvity of the esters at room temperature and competing reactions that lead to large variations in resin pot life structure, with the detection of amide, ester, imine and amine.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

Link

http://journals.sagepub.com/doi/pdf/10.1088/0954-0083/3/2/006

Reference18 articles.

1. [1] P. R. Young and R. Escott, Polyimides (D. Wilson, H. D. Stenzenberger and P. M. Hergenrother (Eds), Blackie, Glasgow (1990), p. 128-128.

2. [3] R. H. Pater, C. Morgan, A. Chang and K. Whitley, Proc. SPE Natl. Tech. Conf, 1450-1450 (1987).

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