X-Ray Scattering from Liquid–Liquid Interfaces

Abstract

We present our recent progress in using synchrotron x-ray surface scattering to study several different aspects of ordering at liquid–liquid interfaces. (1) The interfacial width at the water–alkane interface has been measured for a series of different chain length alkanes. The variation of interfacial width with the carbon number can be described by combining the capillary wave prediction for the width with a contribution from the intrinsic structure. (2) Under appropriate conditions, a surfactant monolayer forms at the interface between water and a hexane solution of a fluorinated surfactant. Reflectivity measurements that probe the electron density profile normal to the interface provide information on the surfactant ordering. This monolayer undergoes a solid to gas transition as a function of temperature. Diffuse scattering near the transition reveals the presence of islands. (3) Equilibrium interfaces between two aqueous phases containing polyethylene glycol and potassium phosphate salts can be studied. We present studies of conformal capillary wave fluctuations between two interfaces of a thin film of this biphase system. We also demonstrate that ferritin can be trapped and studied at this aqueous–aqueous interface.