Fourier Transform Spectroscopy of the B 2Σ-X 2Σ Transition of BaH

Author:

O Appelblad ,L-E Berg ,L Klynning ,J W C Johns

Abstract

The B 2Σ-X 2Σ band system of gaseous barium hydride in the wave length region 8900-11200 Å has been examined in absorption using a King furnace. The spectrum has been obtained by means of Fourier transform spectroscopy. Seven bands have been rotationally analyzed. Term values and molecular constants of the B 2Σ and X 2Σ states have been determined by standard least-squares analysis. The following molecular constants have been derived (cm-1): T e ωe ωe x e ωe y e B e αe 104 × D e B 2Σ+ 11092.593 1088.898 15.471 0.0237 3.26879 0.07061 1.1585 X 2Σ+ 0. 1168.433 14.611 0.0276 3.38226 0.06568 1.1234

Publisher

IOP Publishing

Subject

Condensed Matter Physics,Mathematical Physics,Atomic and Molecular Physics, and Optics

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