Abstract
Abstract
This research aims to investigate the effect of chemical treatment on the integrity of the epoxy coating applied on mild steel substrates. Grit blasted steel samples were chemically treated in 10 vol.% NaOCl solution, 10 vol.% CrCl3 and 30 vol.% H3PO4–5 vol.% HNO3 solutions prior to coating application. Post-cleaning surface morphology and chemical composition revealed the formation of oxidation products on steel surface. Under optimized conditions, a dry film thickness of 135 ± 3 μm of epoxy coating was achieved. The CT2 sample (pre-treated with CrCl3) presented higher coating adhesion strength (∼4.12 MPa) and the lowest rust area of ∼0.03% compared to other chemically treated samples during 720 h of immersion in 5 wt.% NaCl solution. The coating degradation mechanism was evaluated by electrochemical impedance spectroscopy (EIS) after 24, 48, 72 and 120 h of immersion in 3.5 wt. % NaCl solution. EIS analysis of the coated samples pretreated with NaOCl and CrCl3 solutions exhibited low water uptake and limited corrosion due to hindrance in the diffusion of ionic species through the coating. However, coated steel samples pretreated in acidic solutions displayed appreciable corrosion damage as confirmed from salt spray and immersion tests. For instance, the delamination of the CT3 and CT4 (acid pre-treated) coatings was confirmed from the EIS analysis., which represented the formation of a double layer and occurrence of faradaic (corrosion) reactions as the coating-substrate interface, resulting in ∼15%–30% delamination in 120 h of exposure.
Subject
Materials Chemistry,Surfaces, Coatings and Films,Process Chemistry and Technology,Instrumentation
Cited by
2 articles.
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