Effective preparation of superhydrophilic-underwater superoleophobic nanoparticles/polymeric sponges for oil-water separation

Author:

Lin Bo,He Wen-Xu,Jiang Li-Wang,Li Zeng-Tian,Wang Hua-Ying,Wu Ying-Xuan,He Fu-AnORCID,Wu Hui-Jun

Abstract

Abstract The hierarchically-micro/nanoscale rough surface structure and the high surface hydrophilicity are two necessary factors to construct the superhydrophilic-underwater superoleophobic materials for oil-water separation. In this work, an effective method on the fabrication of the superhydrophilic-underwater superoleophobic sponges was developed, in which the mixture of the Fe3O4 nanoparticles or (and) the SiO2 nanoparticles, the chitosan, the polyvinyl alcohol, and the glutaraldehyde was coated on the polymeric sponge by dip-coating to obtain the surface-modified sponges possessing the rough superhydrophilic-underwater superoleophobic surface. The structure of the surface-modified sponges were investigated by TGA, FTIR, WAXD, XPS, SEM, two-dimensional EDS element mapping as well as VSM, and the underwater superoleophobicity of the surface-modified sponges was proved by CH2Cl2 contact angle measurement. Furthermore, the resultant surface-modified sponges exhibited good oil-water separation ability by adsorption and filtration.

Funder

the Special Innovation Project Foundation for Students of Guangdong Common University, China

the College Student Training Program of Guangdong University of Petrochemical Technology, China

the Guangdong province natural science foundation, China

the Innovation Team Research Project of Guangzhou Education, China

the professorial and doctoral scientific research foundation of Huizhou University, China

Publisher

IOP Publishing

Subject

Materials Chemistry,Surfaces, Coatings and Films,Process Chemistry and Technology,Instrumentation

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