Abstract
Abstract
A method to enhance the temperature range in which continuous self-healing fiber-reinforced ceramics (shFRCs) can self-heal is proposed to obtain a new high-temperature structural material. The effect of TiSi2 oxidation on self-healing was investigated using SiC, a typical self-healing agent, and TiSi2, which oxidizes at a lower temperature than SiC. Mixtures of SiC and TiSi2 powders were prepared by wet-mixing, and changes in their high-temperature oxidation behavior were investigated using thermogravimetry/differential thermal analysis. The oxidation of TiSi2 at 1000 °C enhanced the oxidation rate of SiC by 2–3 times. A shFRC consisting of an Al2O3 matrix, an interface layer of SiC and TiSi2, and Al2O3 fiber bundles was fabricated by slurrying and filament-winding. The strength recovery of the shFRC following three-point bending was investigated, and results indicated that the prepared material recovered 50 times faster than conventional shFRCs at 1000 °C. The self-healing improver described in this study can promote the oxidation of self-healing agents via its reaction heat. Thus, this improver may be applied as a practical component of self-healing materials.