A mixed-valent metal–organic ladder linked by pyrazine

Abstract

Abstract We report the synthesis, characterization, and electronic state of a novel mixed-valent metal–organic ladder (MOL) linked by pyrazine (pz). Single-crystal x-ray studies revealed that the MOL has a two-legged ladder-shaped framework, which is composed of a pz-connected Pt dimer with bridging Br ions. The electronic state of the MOL was investigated using x-ray and spectroscopic techniques; the MOL was found to have an electronic state that corresponds to the mixed-valence state of PtII and PtIV. Furthermore, the intervalence charge transfer energy of the MOL has lower than that expected from the tendency of a similar halogen-bridged mixed-valence MOL owing to its unique ‘zig-zag’-shaped legs. These results provide a new insight into the physical and electronic properties of MOL systems.