Predictive ion-electrostatic model of disjoining pressure of synthetic gel structures in coarse-dispersed soil substrates

Author:

Smagin A V,Belyaeva E A,Sadovnikova N B,Sidorova M A,Kokoreva A A

Abstract

Abstract The mechanism of disjoining pressure controlling the swelling and water absorption of gel structures for soil conditioning is discussed. Its quantitative description is based on the fundamental ion-electrostatic model of soil water sorption isotherms containing the phase variable of gel swelling degree and specific surface area index of the soil substrate. The model adequately reproduces the s-shape of soil water sorption isotherms in a wide range of water activity from 0.05 to 0.999 depending on the working doses of hydrogels in the range of 0.05-0.3 mass%. Reinforcement of gel structures with amphiphilic dispersed particles increases the effect of disjoining pressure and water absorption.

Publisher

IOP Publishing

Subject

General Engineering

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