Low growth rate synthesis of GaAs nanowires with uniform size

Abstract

Abstract The growth of nanowires (NWs) with uniform sizes is crucial for future NW-based electronics. In this work, an efficient one-step process is introduced for the growth of uniform gallium arsenide NWs on the native oxide surface of Si, which could be even considered as an alternative for expensive and sophisticated patterning approaches. The proposed strategy considers a Ga pre-deposition step leading to the formation of droplets with homogeneous sizes. That is followed by controlled nucleation of gallium arsenide from those droplets only. Our key to controlling the nucleation of gallium arsenide is to perform the NW growth at temperatures above 580 ± 10 °C and low Ga fluxes. By this method, the statistical distribution of the length and diameter of the vertically grown NWs decreased to about 3%–6% of their averaged values. Moreover, 100% epitaxial growth was realized. Besides, the growth of undesired parasitic islands is addressed and accordingly suppressed. Our study focuses on NW low growth rates, which is so far not investigated in the literature and, could be of great interest e.g. for in situ growth studies.