Revealing roaming on the double Morse potential energy surface with Lagrangian descriptors

Author:

Montoya Francisco GonzalezORCID,Wiggins Stephen

Abstract

Abstract In this paper, we analyse the phase space structure of the roaming dynamics in a 2 degree of freedom potential energy surface consisting of two identical planar Morse potentials separated by a distance. This potential energy surface was previously studied in Carpenter B K et al (2018 Regul. Chaotic Dyn. 23 60–79), and it has two potential wells surrounded by an unbounded flat region containing no critical points. We study the phase space mechanism for the transference between the wells using the method of Lagrangian descriptors.

Funder

Office of Naval Research

Engineering and Physical Sciences Research Council

Publisher

IOP Publishing

Subject

General Physics and Astronomy,Mathematical Physics,Modelling and Simulation,Statistics and Probability,Statistical and Nonlinear Physics

Reference53 articles.

1. Dynamics on the double Morse potential: a paradigm for roaming reactions with no saddle points;Carpenter;Regul. Chaotic Dyn.,2018

2. The roaming atom: straying from the reaction path in formaldehyde decomposition;Townsend;Science,2004

3. Roaming reaction: the third way;Bowman;Phys. Today,2011

4. Roaming radicals;Bowman;Ann. Rev. Phys. Chem.,2011

5. Roaming;Bowman;Mol. Phys.,2014

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