Quantum tunnelling and thermally driven transitions in a double-well potential at finite temperature

Abstract

Abstract We explore dissipative quantum tunnelling, a phenomenon central to various physical and chemical processes, utilizing a model based on a double-well potential. This paper aims to bridge gaps in understanding the crossover from thermal activation to quantum tunnelling, a domain still shrouded in mystery despite extensive research. By numerically investigating a model derived from Caldeira–Leggett’s work on quantum Brownian motion, examining both Lindblad and stochastic Schrödinger dynamics, we offer new insights into the transition states in the crossover region. Contrary to a common belief that temperature strongly dampens all quantum effects, our findings reveal that under certain conditions temperature instead alters the nature of tunnelling from a deterministic and periodic process to a stochastic yet still very quantum phenomenon. This underscores the profound influence of quantum effects on transition rates and the critical role of temperature in modulating tunnelling behaviours. Additionally, we introduce a new model for quantum Brownian motion that takes Lindblad form and is formulated as a modification of the widely known model found in Breuer and Petruccione. In our approach, we remove the zero-temperature singularity resulting in a better description of low-temperature quantum Brownian motion near a potential minima. Despite these advancements, we recognize persistent challenges in accurately simulating the dynamics at extremely low temperatures for arbitrary potentials, particularly those that cannot be closely approximated locally by a quadratic function.