Gradient self-organized dislocation in expanded austenite layer during low-temperature nitriding

Abstract

Abstract A typical nitrogen expanded austenite layer is formed by plasma-based low-energy nitrogen ion implantation (PBLEII) on AISI 304L austenitic stainless steel at a moderate temperature of 380 °C. The dislocation self-organization structure in the nitrogen expanded austenite layer is characterized as an evolution from partial and Lomer-Cottrell dislocations in the inner layer near the interface to multilayer stacking faults in the outer nitrided layer. The self-organized dislocation density and forms are essentially dependent on the plastic deformation, strain-gradient, and nitrogen-related stacking fault energies, respectively, due to the constrained expansion in the nitrided layer. As the nitrogen concentration in the austenitic matrix increases, the stacking fault energy gradually decreases, resulting in the transformation of the defect from Lamer-Cottrell dislocations to multilayer stacking faults. The appropriate stress, which is associated with orderly stress relief during dislocation self-organization, preserves the integrity of the nitrided layer with a combinedly improved in wear and corrosion resistance. Nitriding-induced dislocation self-organization is basically explored as the formation mechanism of the nitrogen expanded austenite layer, contributing to the development of the specific low-temperature nitriding austenitic steel.