Effect of ZnS nanowire ARC on CZTS/CdS thin film solar cell by Nebulizer Spray Pyrolysis Technique

Abstract

Abstract The main intention of this experimental work is to eliminate the reflection of the CZTS/CdS thin film solar cell by depositing the ZnS Antireflection coating (ARC) by Nebulizer Spray Pyrolysis Technique. The CZTS/CdS thin films with and without ZnS Antireflection coating (ARC) deposited using nebulizer spray pyrolysis method is reported in this work. The prepared films were characterized by X-ray diffraction, scanning electron microscopy and UV–Vis spectroscopy analysis. Structural parameters such as lattice constants, texture orientation factor, micro strain, dislocation density and crystallite size were estimated using XRD data. The efficiency of CZTS/CdS solar cell is calculated using I-V characteristics. The experimental results exhibit the short circuit current increased from 9.269 × 10−5A to 1.250 × 10−4A and efficiency raised from 0.21% to o.45%. with ZnS as a ARC. The theoretical quantum efficiency of CZTS solar cell with ZnS ARC is increased from 0.020% to 0.030%. The results indicates that the ZnS ARC is one of the perfect ARC in the CZTS solar cell.