Application of β-diketone boron complex as an ultraviolet absorber in polyvinyl chloride film

Abstract

Abstract In this paper, β-diketone boron complex (BF2-TPE) was first used as an ultraviolet (UV) absorber for polyvinyl chloride (PVC), and then a series of PVC/BF2-TPE composite films were prepared by solvent casting method. UV accelerated aging experiment was conducted to evaluate the effect of BF2-TPE on the photooxidative degradation of PVC, the structure and properties of the composite films in the UV aging process were characterized by ultraviolet-visible absorption spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, dynamic mechanical analysis and mechanical property analysis. The results show that BF2-TPE can absorb UV light in the wavelength range of 220–450 nm. The yield strength of the PVC/BF2-TPE composite film with 0.5% BF2-TPE (PVC/BF2-TPE0.5) decreases from 10.5 MPa to 7.8 MPa after 1200 h of UV irradiation, and its retention ratio is much higher compared with that of pure PVC film, indicating that BF2-TPE can inhibit the photooxidative degradation PVC. The PVC/BF2-TPE0.5 composite film shows higher temperature of onset decomposition, indicating that BF2-TPE can also enhance the thermal stability of PVC/BF2-TPE composite films.