Author:
Arutunow Anna,Zieliński Artur,Tobiszewski Mateusz T.
Abstract
PurposeThe purpose of this paper is to present the results of an atomic force microscopy (AFM) based approach to local impedance spectroscopy (LIS) measurement performed on AA2024 and AA2024‐T3 aluminium alloys.Design/methodology/approachAFM‐LIS measurements were performed ex‐situ without the electrolyte environment, so in fact the electrical not electrochemical impedance was obtained.FindingsRelative local impedance values recorded for AA2024 alloy during the researches carried out were maximally approximately three orders of magnitude higher than the ones obtained for age‐hardened AA2024‐T3 alloy. Moreover, in the case of AA2024‐T3 alloy, a region located in the interior of α crystals exhibited localized impedance one order of magnitude higher than that measured at its grain boundary when affected by intergranular corrosion.Originality/valueThe paper presents differences in localized impedance between grain and grain boundaries activity.
Subject
General Materials Science,General Chemical Engineering
Reference19 articles.
1. ASTM G110‐92 (2009), Standard Practice for Evaluating Intergranular Corrosion Resistance of Heat Treatable Aluminium Alloys by Immersion in Sodium Chloride + Hydrogen Peroxide Solution, ASTM International, West Conshohocken, PA.
2. Campestrini, P., van Westing, E.P.M., van Rooijen, H.W. and de Wit, J.H.W. (2000), “Relation between microstructural aspects of AA2024 and its corrosion behaviour investigated using AFM scanning potential technique”, Corrosion Science, Vol. 42 No. 11, pp. 1853‐61.
3. Darowicki, K. and Zieliński, A. (2010), “Mesoscopic impedance analysis of solid materials' surface”, Electrochimica Acta, Vol. 55 No. 26, pp. 7761‐5.
4. Darowicki, K., Zieliński, A. and Kurzydłowski, K.J. (2008), “Application of dynamic impedance spectroscopy to atomic force microscopy”, Science and Technology of Advanced Materials, Vol. 9 No. 4, p. 045006.
5. Davoodi, A., Pan, J., Laygraf, C. and Norgren, S. (2008), “The role of intermetallics particles in localized corrosion of an aluminium alloy studied by AKPFM and integrated AFM/SECM”, Journal of the Electrochemical Society, Vol. 155 No. 5, pp. C211‐C18.
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